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Oil of Cognac from fusel oil

Brandy flavour distilled from the pressed lees of wine, with oil of vitriol by the half-pound.

From
The French Wine and Liquor Manufacturer
Published
1863
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Exactly as printed, 1863

Oil of Cognac.

The flavor belonging to genuine French brandy is due to a peculiar oil, known as oil of Cognac. This oil is obtained by distillation from the marc, or lees of wine, either dried or made up into cakes, or, in their wet state, mixed with about seven or eight times their weight of water. The brandy from any part of the world may be very closely imitated by distilling the oil from the marc of the wines produced in the particular district. Oil of Cognac is also prepared by dissolving the fusil oil of marc brandy in strong rectified spirit, and then adding a sufficient quantity of concentrated sulphuric acid to form a sulphate; alcohol and excess of acid is removed by washing the newly formed compound with water. To 100 lbs. of marc add ½ lb. sulphuric acid; the oil is generally formed towards the end of the distillation, and is found floating in blackish drops on the surface of the distillate. According to a distinguished French chemist, this oil is a compound of potatoe oil and enanthic ether. Cognac oil when pure, has a true vinous odor, and, like all essential oils, requires to be cut with strong alcohol. One ounce of the pure article is sufficient to flavor from 200 to 250 gallons. The manufacturer should be very careful when using this powerful oil: add a very little at a time, and remember more may be added if necessary.

Oil of Cognac is very generally adulterated with alco hol; indeed, it is extremely difficult to procure the really genuine article. As a test to ascertain whether it is pure, we offer the following simple method:-Take a half ounce phial, and fill it exactly half full with the oil, then fill up the remaining space with water, and shake it well; if the oil is adulterated with alcohol, the latter will leave the former and mix with the water, conse


The French Wine and Liquor Manufacturer, 1863. Public domain; transcription unaltered.

So what happens if I make it?

Half a pound of oil of vitriol to a hundred pounds of marc, and then more concentrated acid for the esterification. This is bench chemistry with a strong corrosive, written for a workshop rather than a laboratory.

The entry then admits the product is “very generally adulterated” and offers a test to detect it — which tells you how much of the trade's brandy flavour was neither brandy nor flavour.

Notes from the 21st century

  • Fusel oil is the discarded fraction. The heavy tail of a distillation, chiefly isoamyl alcohol. Distillers cut it out because it is harsh and gives fierce hangovers.
  • Marc and lees. Marc is the pressed skins, pips and stems left after winemaking; lees are the cask sediment. Both are genuine brandy feedstock.
  • The test is the useful part. Half-fill a phial with the oil and top it with water; the book's method for spotting alcohol adulteration still works.

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